|本期目录/Table of Contents|

[1]宋安东,冯新军,谢慧,等.合成气制取乙醇2种技术比较分析[J].生物加工过程,2012,10(05):72-78.[doi:10.3969/j.issn.1672-3678.2012.05.014]
 SONG Andong,FENG Xinjun,XIE Hui,et al.Comparative analysis on two technologies of ethanol production from syngas[J].Chinese Journal of Bioprocess Engineering,2012,10(05):72-78.[doi:10.3969/j.issn.1672-3678.2012.05.014]
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合成气制取乙醇2种技术比较分析()
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《生物加工过程》[ISSN:1672-3678/CN:32-1706/Q]

卷:
10
期数:
2012年05期
页码:
72-78
栏目:
出版日期:
2012-09-30

文章信息/Info

Title:
Comparative analysis on two technologies of ethanol production from syngas
文章编号:
1672-3678(2012)05-0072-07
作者:
宋安东冯新军谢慧王风芹
河南农业大学 生命科学学院 农业部农业微生物酶工程重点实验室,郑州 450002
Author(s):
SONG AndongFENG XinjunXIE HuiWANG Fengqin
Key Laboratory of Enzyme Engineering of Agricultural Microbiology of the Ministry of Agriculture, College of Life Science,Henan Agricultural University,Zhengzhou 450002,China
关键词:
乙醇 合成气 费托合成法 微生物厌氧发酵法
分类号:
Q815
DOI:
10.3969/j.issn.1672-3678.2012.05.014
文献标志码:
A
摘要:
论述了合成气制取乙醇的必要性,重点对以合成气为原料制取燃料乙醇的化学催化法(费托合成法)和厌氧发酵法两种技术的优缺点进行对比分析,指出了利用合成气通过厌氧发酵技术来生产乙醇具有显著的优势,同时也提出了合成气厌氧发酵制取乙醇技术中存在的问题和建议。

参考文献/References:

[1] 李东,袁振宏,王忠铭,等.生物质合成气发酵生产乙醇技术的研究进展[J].可再生能源,2006,126:57-61.
[2] US Department of Energy,Office of the Biomass Program.Biomass program multi-year technical plan[M].Washington,D.C.:[s.n.],2003.
[3] 王鹏,王宪贵,郭战英,等.合成气合成乙醇的研究进展[J].洁净煤技术,2010(1):5-62.
[4] Phillips J R,Clausen E C,Gaddy J L,et al.Biological production of ethanol from coal synthesis gas[J].Appl Biochem Biotechnol,1993,39-40(1):559-571.
[5] Maschio G,Lucchesi A,Stoppato G.Production of syngas from biomass[J].Bioresour Technol,1994,48(2):119-126.
[6] 覃国军.石油石化企业面临的低碳发展挑战和机遇[J].油气田环境保护,2010,20(1):1-4.
[7] Zhu Xiangxue,Chen Fucun,An Jie,et al.Development and industrialization of the ethylbenzene production technologies from dilute ethylene in FCC dry gas[J].Adv Mats Res,2011,233-235:1708-1713.
[8] 王连中,姜国生,王兰成.炼厂干气回收烃类作为乙烯装置原料的可行性论证[J].化工设计,2004,14(2):43-45.
[9] 蓝平,蓝丽红,谢涛,等.生物质合成气制备及合成液体燃料研究进展[J].化学世界,2011(7):437-441.
[10] 士丽敏,储伟,刘增超.合成气制低碳醇用催化剂的研究进展[J].化工进展,2011,30(1):162-166.
[11] Haider M A,Gogate M R,Davis R J.Fe-promotion of supported Rh catalysts for direct conversion of syngas to ethanol[J].J Catal,2009,261(1):9-16.
[12] 寇元.合成气催化转化的绿色化学[J].催化学报,2008,29(9):817-822.
[13] Kharas K,Durand J P.Cobalt-molybdenum sulfide catalyst materials and methods for ethanol production from syngas:US,20090069609[P].2009-03-12.
[14] Barik S,Prieto S,Harrison S B,et al.Biological production of alcohols from coal through indirect liquefaction[J].Appl Biochem Biotechnol,1988,18(1):363-378.
[15] Abrini J,Naveau H,Nyns E J.Clostridium autoethanogenum sp.nov.,an anaerobic bacterium that produces ethanol from carbon monoxide[J].Arch Microbiol,1994,161(4):345-351.
[16] Rajagopalan S,Datar R P,Lewis R S.Formation of ethanol from carbon monoxide via a new microbial catalyst[J].Biomass Bioenergy,2002,23(6):487-493.
[17] 郭颖,许敬亮,徐惠娟,等.Clostridium autoethanogenum的生长培养基优化[J].可再生能源,2011,29(1):53-56.
[18] 张兰波,刘继开,李东,等.合成气乙醇发酵的微生物研究[J].可再生能源,2007,25(3):27-30.
[19] Hurst K M,Lewis R S.Carbon monoxide partial pressure effects on the metabolic process of syngas fermentation[J].Biochem Eng J,2010,48(2):159-165.
[20] Köpke M,Held C,Hujer S,et al.Clostridium ljungdahlii represents a microbial production platform based on syngas[J].PNAS,2010,107(29):13087-13092.
[21] Wilkins M R,Atiyeh H K.Microbial production of ethanol from carbon monoxide[J].Curr Opin Biotech,2011,22(3):326-330.
[22] Abubackar H N,Veiga M C,Kennes C.Biological conversion of carbon monoxide:rich syngas or waste gases to bioethanol[J].Biofuels,Biopro Bioref,2011,5(1):93-114.
[23] Munasinghe P C,Khanal S K.Biomass-derived syngas fermentation into biofuels:opportunities and challenges[J].Bioresour Technol,2010,101(13):5013-5022.
[24] Klasson K T,Ackerson C M D,Clausen E C,et al.Bioreactor design for synthesis gas fermentations[J].Fuel,1991,70(9):605-614.
[25] Saxena J,Tanner R S.Effect of trace metals on ethanol production from synthesis gas by the ethanologenic acetogen,Clostridium ragsdalei[J].J Ind Microbiol Biotechnol,2011,38(4):513-521.
[26] Guo Y,Xu J,Zhang Y,et al.Medium optimization for ethanol production with Clostridium autoethanogenum with carbon monoxide as sole carbon source[J].Bioresour Tech,2010,101(22):8784-8789.
[27] Kendall M H,Randy S L.Carbon monoxide partial pressure effects on the metabolic process of syngas fermentation[J].Biochem Eng J,2010,48(2):159-165.
[28] Liou J C,Balkwill D L,Drake G R,et al.Clostridium carboxidivorans sp.nov.,a solvent-producing Clostridium isolated from an agricultural settling lagoon,and reclassification of Clostridium scatologenes strain SL1 as Clostridium drakei sp.nov.[J].Int J Syst Evol Microbiol,2005(55):2085- 2091.
[29] Klasson K T,Ackerson C M D,Clausen E C,et al.Biological conversion of synthesis gas into fuels[J].Int Assoc Hydrogen Energy,1992,17(4):281-288.
[30] 郭颖,许敬亮,徐惠娟,等.合成气和培养基组分对C.autoethanogenum发酵产乙醇的影响研究[J].太阳能学报,2011,32(9):1370-1374.
[31] Gaddy J L,Clausen E C.Clostridium ljungdahlii an anaerobic ethanol and acetate producing microorganism:US,5173429[P].1992-12-22.
[32] Kundiyana D K,Huhnke R L,Wilkins M R.Syngas fermentation in a 100-L pilot scale fermentor:design and process considerations[J].J Biosci Bioeng,2010,109(5)492-498.
[33] 李东,袁振宏,吕鹏梅,等.合成气生物利用的研究进展[J].生物质化学工程,2007,41(2):54-58.
[34] 闫强,王安建,王高尚.全球生物质能源评价[J].中国农学通报,2009,25(18):466-470.
[35] 中华网.携手中科院新西兰LanzaTeck公司,河南煤业化工集团公司进军清洁能源领域[N/OL].[2011-12-10].http://henan.china.com/zh_cn/finance/pinpai/11084294/20100907/16130237.html.
[36] 金融界.宝钢联手中科院等合作探索钢厂尾气制乙醇新技术[N/OL].[2011-12-10].http://finance.jrj.com.cn/industry/2011/03/2809239577373.shtml.
[37] 徐惠娟,许敬亮,郭颖,等.合成气厌氧发酵生产有机酸和醇的研究进展[J].中国生物工程杂志,2010,30(3):112-118.
[38] 宋安东,冯新军,谢慧,等.生物质合成气发酵制取燃料乙醇研究进展[J].食品与发酵工业,2011,37(6):130-136.
[39] Grethlen A J,Mahendra.Bioprocessing of coal-derived synthesis gases by anaerobic bacteria[J].Trends Biotech,1992,10(12):418-423.
[40] Grethlen A J,Sonib K,Worden R M,et al.Influence of hydrogen sulfide on the growth and metabolism of Butyribacterium methylotrophicum and Clostridium acetobutylicum[J].J Appl Biochem,1992,34-35(1):233-246.
[41] Vega J L,Klasson K T,Kimmel D E,et al.Sulfur gas tolerance and toxicity of CO-utilizing and methanogenic bacteria[J].Appl Biochem Biotechnol,1990,24-25(1):329-340.

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备注/Memo

备注/Memo:
收稿日期:2011-12-13
基金项目:河南省省院科技合作专项资金资助项目(102106000018)
作者简介:宋安东(1972─),男,河南宜阳人,博士,教授,研究方向:微生物能源工程、生物质转化与利用技术与工程,E-mail:song1666@126.com.
更新日期/Last Update: 2012-09-30