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[1]李全顺,高贵,李广泉,等.脂肪酶催化的末端官能化聚酯合成研究进展[J].生物加工过程,2009,7(02):1-7.
 undefinedundefinedundefined LI Quan-shun,GAO Gui,LI Guang-quan,et al.Development of lipase-catalyzed synthesis in terminal-functionalized polyesters[J].Chinese Journal of Bioprocess Engineering,2009,7(02):1-7.
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脂肪酶催化的末端官能化聚酯合成研究进展
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《生物加工过程》[ISSN:1672-3678/CN:32-1706/Q]

卷:
7
期数:
2009年02期
页码:
1-7
栏目:
出版日期:
2009-03-30

文章信息/Info

Title:
Development of lipase-catalyzed synthesis in terminal-functionalized polyesters
文章编号:
1672-3678(2009)02-0001-07
作者:
李全顺高贵李广泉冯雁
吉林大学 分子酶学工程教育部重点实验室,长春130023
Author(s):
undefinedundefinedundefined

LI Quan-shunGAO GuiLI Guang-quanFENG Yan

Key Laboratory for Molecular Enzymology & Engineering of the Ministry of Education,Jilin University,Changchun 130023,China
关键词:
酶化学法脂肪酶聚酯聚合末端官能化聚酯
分类号:
TQ316.341
文献标志码:
A
摘要:
脂肪酶催化的末端官能化聚酯合成是高分子合成领域中极具吸引力且发展非常迅速的重要技术。重点介绍引发剂法、终止剂法以及酶促化学偶联合成末端官能化聚酯研究所取得的主要进展。

参考文献/References:

[1]Fujimaki T. Processability and properties of aliphatic polyesters,‘BIONOLLE’,synthesized by polycondensation reaction[J]. Polym Degrad Stabil,1998,59: 209-214.
[2]Gross R A,Kumar A,Kalra B. Polymer synthesis by in vitro enzyme catalysis[J]. Chem Rev, 2001,101: 2097-2124.
[3]Kobayashi S,Uyama H,Kimura S. Enzymatic polymerization[J]. Chem Rev,2001,101: 3793-3818.
[4]Varma I K,Albertsson A C,Rajkhoma R,et al. Enzyme catalyzed synthesis of polyesters[J]. Prog Polym Sci,2005,30: 949-981.
[5]Albertsson A C,Srivastava R K. Recent developments in enzyme-catalyzed ring-opening polymerization[J]. Adv Drug Deliver Rev,2008,60(9): 1077-1093.
[6]Uyama H,Suda S,Kobayashi S. Enzymatic synthesis of terminal-functionalized polyesters by initiator method[J]. Acta Polym,1998,49: 700-703.
[7]Uyama H,Kikuchi H,Kobayashi S. One-shot synthesis of polyester macromonomer by enzymatic ring-opening polymerization of lactone in the presence of vinyl ester[J]. Chem Lett,1995,24(11): 1047-1048.
[8]Takwa M,Xiao Y,Simpson N,et al. Lipase catalyzed HEMA initiated ring-opening polymerization: in situ formation of mixed polyester methacrylates by transesterification[J]. Biomacromolecules,2008,9: 704-710.
[9]马玖彤,李全顺,王元鸿,等. 引发剂对酶促开环聚合ε己内酯的影响[J]. 生物加工过程,2006,4(6): 2631.
Ma Jiutong,Li Quanshun,Wang Yuanhong,et al. Effect of initiators on enzyme-catalyzed ring-opening polymerization of ε-caprolactone[J].Chinese Journal of Bioprocess Engineering,2006,4(6): 26-31.
[10]Numata K,Srivastava R K,Finne-Wistrand A,et al. Branched poly(lactide) synthesized by enzymatic polymerization: effects of molecular branches and stereochemistry on enzymatic degradation and alkaline hydrolysis[J]. Biomacromolecules,2007,8(10): 3115-3125.
[11]He F,Li S,Vert M,et al. Enzyme-catalyzed polymerization and degradation of copolymers prepared from ε-caprolactone and poly(ethylene glycol)[J]. Polymer,2003,44: 5145-5151.
[12]Srivastava R K,Albertsson A C. Enzyme-catalyzed ring-opening polymerization of seven-membered ring lactones leading to terminal-functionalized and triblock polyesters[J]. Macromolecules,2006,39: 46-54.
[13]Kumar A,Gross R A,Wang Y,et al. Recognition by lipases of ω-hydroxyl macroinitiators for diblock copolymer synthesis[J]. Macromolecules,2002,35: 7606-7611.
[14]Zhou J,Wang W,Thurecht K J,et al. Simultaneous dynamic kinetic resolution in combination with enzymatic ring-opening polymerization[J]. Macromolecules,2006,39: 7302-7305.
[15]Iwata S,Toshima K,Matsumura S. Enzyme-catalyzed preparation of aliphatic polyesters containing thioester linkages[J]. Macromol Rapid Commun,2003,24: 467-471.
[16]Hedfors C,Ostmark E,Malmstrom E,et al. Thiol end-functionalization of poly(ε-caprolactone),catalyzed by Candida antarctica lipase B[J]. Macromolecules,2005,38: 647-649.
[17]Takwa M,Simpson N,Malmstrom E,et al. One-pot difunctionalization of poly(ω-pentadecalactone) with thiol-thiol or thiol-acrylate groups,catalyzed by Candida antarctica lipase B[J]. Macromol Rapid Commun,2006,27: 1932-1936.
[18]Henderson L A,Svirkin Y Y,Gross R A,et al. Enzyme-catalyzed polymerization of ε-caprolactone: effects of initiator on product structure,propagation kinetics,and mechanism[J]. Macromolecules,1996,29: 7759-7766.
[19]Marzorati M,Hult K,Riva S,et al. Incorporation of primary amines into a polyester chain by a combination of chemical and lipase-catalyzed ε-caprolactone ring-opening processes[J]. Adv Synth Catal,2007,349: 1963-1968.
[20]Marzorati M,Navarra C,Mendichi R,et al. Incorporation of primary amines into a poly(1,5-dioxepan-2-one) via lipase-catalyzed ring-opening polymerization[J]. J Mol Catal B: Enzym,2008,52-53: 158-161.
[21]Cordova A,Iversen T,Hult K.Lipase-catalyzed synthesis of methyl 6-O-poly(ε-caprolactone)glycopyranosides[J].Macromolecules,1998,31: 1040-1045.
[22]Bisht K S,Deng F,Gross R A,et al. Ethyl glycoside as a multifunctional initiator for enzyme-catalyzed regioselective lactone ring-opening polymerization[J]. J Am Chem Soc,1998,120: 1363-1367.
[23]Li J,Xie W,Cheng H N,et al. Polycaprolactone-modified hydroxyethylcellulose films prepared by lipase-catalyzed ring-opening polymerization[J]. Macromolecules,1999,32: 2789-2792.
[24]Fujioka M,Okada H,Kusaka Y,et al. Enzymatic synthesis of chitin- and chitosan-graft-aliphatic polyesters[J]. Macromol Rapid Commun,2004,25: 1776-1780.
[25]Kumar R,Gross R A. Biocatalytic route to well-defined macromers built around a sugar core[J]. J Am Chem Soc,2002,124: 1850-1851.
[26]Uyama H,Kikuchi H,Kobayashi S. Single-step acylation of polyester terminals by enzymatic ring-opening of 12-dodecanolide in the presence of acyclic vinyl esters[J]. Bull Chem Soc Jpn,1997,70: 1691-1695.
[27]Meyer U,Palmans A R A,Loontjens T,et al. Enzymatic ring-opening polymerization and atomic transfer radical polymerization from a bifunctional initiator[J]. Macromolecules,2002,35: 2873-2875.
[28]Peters J,Palmans A R A,Veld M,et al. Cascade synthesis of chiral block copolymers combining lipase catalyzed ring opening polymerization and atom transfer radical polymerization[J]. Biomacromolecules,2004,5: 1862-1868.
[29]Kalra B,Kumar A,Gross R A,et al. Chemoenzymatic synthesis of new brush copolymers comprising poly(ω-pentadecalactone) with unusual thermal and crystalline properties[J]. Macromolecules,2004,37: 1243-1250.
[30]van As B A C,Thomassen P,Kalra B,et al. Onepot chemoenzymatic cascade polymerization under kinetic resolution conditions[J]. Macromolecules,2004,37: 8973-8977.
[31]Duxbury C J,Wang W,de Geus M,et al. Can block copolymers be synthesized by a single-step chemoenzymatic route in supercritical carbon dioxide[J]. J Am Chem Soc,2005,127: 2384-2385.
[32]Villarroya S,Zhou J,Thurecht K J,et al. Synthesis of graft copolymers by the combination of ATRP and Enzymatic ROP in scCO2[J]. Macromolecules,2006,39: 9080-9086.
[33]Srivastava R K,Kumar K,Varma I K,et al. Chemo-enzymatic synthesis of comb polymers[J]. Eur Polym J,2007,43: 808-817.
[34]Sha K,Li D,Wang S,et al. Synthesis and characterization of diblock copolymer by enzymatic polymerization and ATRP from a novel bifunctional initiator[J]. Polym Bull,2005,55: 349-355.
[35]Sha K,Qin L,Li D,et al. Synthesis and characterization of diblock and triblock copolymer by enzymatic ring-opening polymerization of ε-caprolactone and ATRP of styrene[J]. Polym Bull,2005,54: 1-9.
[36]Sha K,Li D,Li Y,et al. Synthesis,characterization,and micellization of an epoxy-based amphiphilic diblock copolymer of ε-caprolactone and glycidyl methacrylate by enzymatic ring-opening polymerization and atom transfer radical polymerization[J]. J Polym Sci,Part A: Polym Chem,2007,45: 5037-5049.
[37]Sha K,Li D,Li Y,et al. The chemoenzymatic synthesis of a novel CBABC-type pentablock copolymer and its self-assembled “crew-cut” aggregation[J]. Macromolecules,2007,41: 361-371.
[38]Skaria S,Smet M,Frey H. Enzyme-catalyzed synthesis of hyperbranched aliphatic polyesters[J]. Macromol Rapid Commun,2002,23: 292-296.
[39]Ai P,Chen L,Hu D,et al. Synthesis of hyperbranched copolymers by combining enzymatic ring-opening polymerization and ATRP from a novel bifunctional initiator[J]. Chinese Sci Bull,2006,51: 2706-2709.
[40]van As B A C,van Buijtenen J,Heise A,et al. Chiral oligomers by iterative tandem catalysis[J]. J Am Chem Soc,2005,127(28): 9964-9965.
[41]van Buijtenen J,van As B A C,Meuldijk J,et al. Chiral oligomers by iterative tandem catalysis[J]. Chem Commun,2006: 3169-3171.

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备注/Memo

备注/Memo:
收稿日期:2008-05-05
基金项目:国家高技术研究发展计划(863计划)资助项目(2006AA020203,2007AA021306);吉林省科技厅高技术重点资助项目(20050312);吉林大学“985工程”研究生创新基金资助项目(20080220)
作者简介:李全顺(1981—),男,山西大同人,博士研究生,研究方向:生物催化合成功能高分子材料;冯雁(联系人),教授,E-mail:yfeng@mail.jlu.edu.cn
更新日期/Last Update: